Diffusion Coefficients of Ferrocene and Ferricinium Ion in Tetraethylammonium Perchlorate Acetonitrile Solutions, as Determined by Chronoamperometry
نویسندگان
چکیده
منابع مشابه
Benchmark Calculations of Absolute Reduction Potential of Ferricinium/Ferrocene Couple in Nonaqueous Solutions.
High-level ab initio molecular orbital theory is used to obtain benchmark values for the ferricenium/ferrocene (Fc(+)/Fc) couple, the IUPAC recommended reference electrode for nonaqueous solution. The gas-phase ionization energy of ferrocene is calculated using the high-level composite method, G3(MP2)-RAD, and two higher-level variants of this method. These latter methods incorporate correction...
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Department of Applied Physics, University of Fukui, Bunkyo 3-9-1, Fukui, 910-8507 Japan Abstract Sodium alginate solution, being viscous hydrocolloid, was examined voltammetrically in the context of viscous effects by use of a ferrocenyl compound as a redox probe. Voltammograms were almost independent of concentrations of sodium alginate even in a solid-like state. Diffusion coefficients of the...
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ژورنال
عنوان ژورنال: Electrochemistry
سال: 2001
ISSN: 1344-3542,2186-2451
DOI: 10.5796/electrochemistry.69.34